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Batch
Wet Process
Still Dominates
Wafer-Cleaning Market
But for How Long?

Bijan
Moslehi, PhD, is chief technology officer and senior vice president, semiconductor technology research, for The Noblemen Group (www.noblemengroup. com), a boutique investment banking, strategic advisory, and business development firm based in San Diego, Silicon Valley, Seoul, and Portland, OR. Moslehi has some 20 years' experience working
in the semiconductor and semiconductor equipment industries, including stints with Hewlett-Packard, VLSI Technology, Philips, National Semiconductor, Fairchild Semiconductor, Applied Materials, KLA-
Tencor, and Mattson. He can be reached at bmoslehi@noblemengroup.com.
There
are more than 100 cleaning steps in a deep-submicron semiconductor manufacturing
process flow. With each new technology node, the number of cleanings
has risen. The main factor behind this trend is the increasing number
of mask layers, particularly in the metal-interconnect area. Progressively
stringent contamination and cross-contamination control requirements
have also contributed to the demand for more cleans. Consequently, wafer-cleaning
tools have evolved into fully automated systems with sophisticated equipment
and process control capabilities.
Batch-cleaning
tools, both immersion and spray type, are among the few remaining batch
systems in leading-edge wafer fabs. Batch tools still command the lion's
share of the wet clean and surface preparation equipment markets. Despite
claims by some industry experts in the early 1990s that wet tools would
be eliminated from fabs by the end of the last century, batch systems
continue to be mainstays in today's fabs. This is because of batch tools'
continuing ability to meet demanding process specifications and operational
requirements. The selection of these tools is driven by the same factors
as other types of fab equipment: process performance, high productivity,
high throughput, and low cost of ownership (COO).
Batch
wet tools account for around 80% of the total wet clean market, with
single-wafer spin/spray tools and scrubbers making up the remaining
portion. Unfortunately for equipment makers, batch immersion tools tend
to be extremely price sensitive, with low margins and generally high
field service and support costs. It has also been difficult to establish
and maintain any significant technical differentiation in the automated
wet-station market. Consequently, running a profitable auto-wet tool
business has been quite difficult.
Although
there have been numerous advances in batch wet-cleaning tool performance
in the past decade, the financial performance of the companies that
manufacture those tools has seen little improvement. As a result, there
has been significant consolidation in the market, with a few companies
exiting the space. Unless one of the surviving suppliers develops a
significant form of sustainable competitive differentiation based on
patent-protected intellectual property, the difficult economic conditions
will likely persist in the batch-cleaning space.
On
the process technology front, wet-cleaning solutions for batch tools
have evolved from concentrated chemistries into more-dilute mixtures,
resulting in much lower chemical usage. Significant efforts have also
been made to reduce DI-water consumption. Furthermore, better process
control has resulted in improved process results. The push for higher
productivity in auto-wet immersion tools has led to a shift from huge
systems with many tanks to tools with much smaller footprints and fewer
tanks.
Reduced
cleans with dilute chemistries in new batch single-tank systems offer
higher productivity and throughputs, shorter cycle times, lower chemical
consumption, and an even smaller footprint than previous versions, increasing
their appeal to 300-mm fabs. All major suppliers offer reduced-footprint/
single-tank tools, and more and more fabs have adopted them for critical
cleaning processes.
The
adoption of single-wafer cleaning technology has been under way since
the early 1990s. Single-wafer scrubbers are widely used for particle
removal in back-end-of-line (BEOL) processes. Stand-alone single-wafer
spin/spray processors have been primarily employed for enabling side-selective
cleaning applications, such as backside particle removal (prelitho clean),
backside film strips (mainly in front-end-of-line [FEOL] steps), backside
and bevel-edge cleans (BEOL copper contamination removal), and wafer
thinning.
Generally,
these side-selective single-wafer applications have not taken any significant
market share away from batch tools because they have created new markets
for new and unique cleaning applications. However, more-recent single-wafer
tools, designed for some conventional BEOL cleaning applications, are
in direct competition with batch tools. In particular, there is a growing
interest in using single-wafer wet cleans following BEOL dry-resist-strip
steps. This application promises to be the largest near-term growth
area for single-wafer spin/spray processors and certainly will enhance
their overall market position at the expense of batch tools.
Cryogenic
aerosol particle removal has found some niche BEOL applications but
has not been widely adopted as a viable mainstream cleaning technique.
Other new and exotic single-wafer cleaning technologies under development,
including laser-assisted cleaning, have yet to be proven in the field.
Historically,
the comparatively low throughput and productivity, and the high cost
of single-wafer cleaning systems have been barriers to the technology's
broad adoption for critical applications. However, certain system makers
have tried to address these issues by offering multichamber, single-wafer
wet-processing systems. The expected increases in throughput and productivity
of these multichamber single-wafer systems will help narrow the operational
gap with batch tools.
Single-wafer
tools also promise to reduce chemical and DI-water consumption, while
at the same time offering the potential to improve process control and
uniformity. The importance of the aforementioned factors has driven
an increased level of interest in single-wafer wet technology as chipmakers
map their strategies for converting to 300-mm wafers. Single-wafer cleaning
technology is of particular interest to fabs with high product mixes
and smaller average lot sizes, although fabs with high-volume runners
may have less-compelling operational reasons to switch to single-wafer
systems.
In
certain applications, momentum is building for the integration of wet
cleans with dry-process tools. The integrated-cleaning strategy potentially
provides better process control, shorter overall cycle time, improved
overall equipment efficiency, and better COO than the existing stand-alone
approach. However, the successful introduction of a high-productivity
tool is contingent on the availability of high-reliability cleaning
modules.
This
trend, if successful, would pose a serious threat to stand-alone single-wafer
cleaning tools, as was demonstrated by the rapid integration of the
post-CMP clean in the late 1990s and the demise of the stand-alone single-wafer
post-CMP scrubber market. Integrated post-CMP cleaning was an enabling
technology driven by process requirements and the need for dry-in/dry-out
wafers. More recently, backside and bevel cleans have been integrated
with copper plating tools. Dielectric etch and dry-strip tools have
emerged as prime candidates for the next wave of wet-cleaning integration,
particularly for BEOL applications. Integrating BEOL applications and
cleaning is much sought after and has several (primarily operational)
advantages. However, successful integration of dry and wet cleans in
a cluster tool requires significant tool and process development effort.
Issues that must be addressed include interfacing (dry) vacuum and (wet)
atmospheric chambers, dry/wet cluster throughput matching, and process
module integration.
The
integration of wet precleans with thermal processes would provide better
control over the quality of the gate stack. But the stringent requirements
for an atomically clean surface/interface, the success of existing batch
tools in this area, and the lack of truly capable and practical FEOL
single-wafer clean modules have made this difficult to achieve. For
instance, the move to single- chemistry solutions for FEOL applications
was not successfully adopted by the industry, despite the tremendous
performance of systems using these new processes.
One
important operational reason for the industry's reticence to embrace
drastic chemistry changes in the wet space is that many larger fabs
often run multiple process technology nodes and multiple products concurrently
on common wet-cleaning tools. In general, any change to the process
of record that could potentially alter process, device performance,
and reliability may require extensive and expensive process and product
requalification, which would be time-consuming and quite cumbersome.
Given the financial performance and complexity of the industry as a
whole, this is just the kind of extra expense and high-risk action that
senior industry executives and fab managers avoid.
In next month's
Reality Check, I will continue my examination of the wafer-cleaning
space. I will focus on the emergence of dry techbnologies such as supercritical
carbon dioxide, and then take a high-altitude view of the whole wafer-cleaning
landscape today.

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